Write about the nitration reaction of benzene.

Vedclass pdf generator app on play store
Vedclass iOS app on app store
(N/A) . Chemical reaction for nitration: When benzene is treated with a mixture of concentrated nitric acid $(HNO_{3})$ and concentrated sulfuric acid $(H_{2}SO_{4})$ at $323 \ K$ to $333 \ K$,it undergoes nitration to form nitrobenzene.
$C_{6}H_{6} + HNO_{3} \xrightarrow{conc. H_{2}SO_{4}, 323-333 \ K} C_{6}H_{5}NO_{2} + H_{2}O$
$b$. Mechanism of formation of the nitronium ion $(NO_{2}^{+})$:
Step-$I$:
$H_{2}SO_{4} + HNO_{3} \rightleftharpoons H_{2}NO_{3}^{+} + HSO_{4}^{-}$
Step-$II$:
$H_{2}NO_{3}^{+} \rightleftharpoons H_{2}O + NO_{2}^{+}$
Overall reaction for the generation of the electrophile:
$H_{2}SO_{4} + HNO_{3} \rightleftharpoons NO_{2}^{+} + HSO_{4}^{-} + H_{2}O$
In this reaction,$H_{2}SO_{4}$ acts as a proton donor (acid) and $HNO_{3}$ acts as a proton acceptor (base),facilitating the formation of the electrophilic nitronium ion $(NO_{2}^{+})$.

Explore More

Similar Questions

$C_6H_6$ $\xrightarrow{CH_3COCl/AlCl_3} A$ $\xrightarrow{Zn-Hg/HCl} B$
The end product in the above sequence is:

In the nitration of benzene by mixed acid,the rate of reaction will be:

Difficult
View Solution

Which of the following is a hydrocarbon?

The conversion of benzene to toluene is carried out by .........

Difficult
View Solution

Given below are two statements. One is labelled as Assertion $A$ and the other is labelled as Reason $R$.
Assertion $A$: $[6]-$Annulene,$[8]-$Annulene and cis$-10-$Annulene are respectively aromatic,non-aromatic and non-aromatic.
Reason $R$: Planarity is one of the requirements of aromatic systems.
In the light of the above statements,choose the most appropriate answer from the options given below.

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Live online exams with unlimited students, 360° analytics & white-label branding.

See Demo